Size-dependent thermodynamic description of the binary Pb-Sn system
J. Min. Metall. Sect. B-Metall. 53 (3) B (2017) 233-238. DOI:10.2298/JMMB170525019G
Full text (pdf)
Export manuscript information:
RIS Format (EndNote, Reference Manager), BibTeX
Abstract
Recently, a new thermodynamic description of the binary Pb – Sn system was proposed and it seems to be interesting to extend this description on the system, where size of particles plays a key-role. To obtain this goal a set of surface Gibbs energies was calculated and added to Gibbs energies describing bulk phases. The extended thermodynamic description was used for calculation of size-dependent phase diagram of binary Pb-Sn system. Comparison of calculation with limited literature information allows for statement that the proposed model is in good agreement with experiment.
Keywords: Thermodynamics; Nano; Calphad; Lead-free solder.Correspondence Address:
W. Gierlotka,
National Dong Hwa University,
Hualien, Taiwan (R.O.C.)
This email address is being protected from spambots. You need JavaScript enabled to view it.

This work is licensed under a
Creative Commons Attribution-
ShareAlike 4.0 International License
W. Gierlotka,
National Dong Hwa University,
Hualien, Taiwan (R.O.C.)
This email address is being protected from spambots. You need JavaScript enabled to view it.

This work is licensed under a
Creative Commons Attribution-
ShareAlike 4.0 International License